If you want to have more then one WordPress website but still have all purchases processed using your one Zen-Cart shop then you can do this with zenWP.
These are the steps:

1. Create a 2nd WordPress site
2. Install and configure zenWP plugin in the normal manner, edit zenWP and make these changes:
   define(‘ZC_URL’, SITE_URL . ‘/’.ZC_FOLDER); //URL for ZC shop
   define(‘ZC_URL’, http://your-shop-domain.com/’.ZC_FOLDER); //URL for ZC shop
3. Get category ID(s), create new category or use existing in ZC
4. In phpMyAdmin export these tables:
   zen_categories, zen_featured, zen_products, zen_products_attributes, zen_products_description, zen_products_options, zen_products_options_types, zen_products_options_values, zen_products_options_values_to_products_options, zen_products_to_categories, zen_specials, zen_tax_class and zen_tax_rates
   and import them into the DB of your new site

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